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The term attribute transfer refers to the tasks of altering images in such a way, that the semantic interpretation of a given input image is shifted towards an intended direction, which is quantified by semantic attributes. Prominent example applications are photo realistic changes of facial features and expressions, like changing the hair color, adding a smile, enlarging the nose or altering the entire context of a scene, like transforming a summer landscape into a winter panorama. Recent advances in attribute transfer are mostly based on generative deep neural networks, using various techniques to manipulate images in the latent space of the generator.
In this paper, we present a novel method for the common sub-task of local attribute transfers, where only parts of a face have to be altered in order to achieve semantic changes (e.g. removing a mustache). In contrast to previous methods, where such local changes have been implemented by generating new (global) images, we propose to formulate local attribute transfers as an inpainting problem. Removing and regenerating only parts of images, our Attribute Transfer Inpainting Generative Adversarial Network (ATI-GAN) is able to utilize local context information to focus on the attributes while keeping the background unmodified resulting in visually sound results.
Generative adversarial networks are the state of the art approach towards learned synthetic image generation. Although early successes were mostly unsupervised, bit by bit, this trend has been superseded by approaches based on labelled data. These supervised methods allow a much finer-grained control of the output image, offering more flexibility and stability. Nevertheless, the main drawback of such models is the necessity of annotated data. In this work, we introduce an novel framework that benefits from two popular learning techniques, adversarial training and representation learning, and takes a step towards unsupervised conditional GANs. In particular, our approach exploits the structure of a latent space (learned by the representation learning) and employs it to condition the generative model. In this way, we break the traditional dependency between condition and label, substituting the latter by unsupervised features coming from the latent space. Finally, we show that this new technique is able to produce samples on demand keeping the quality of its supervised counterpart.
Generative adversarial networks (GANs) provide state-of-the-art results in image generation. However, despite being so powerful, they still remain very challenging to train. This is in particular caused by their highly non-convex optimization space leading to a number of instabilities. Among them, mode collapse stands out as one of the most daunting ones. This undesirable event occurs when the model can only fit a few modes of the data distribution, while ignoring the majority of them. In this work, we combat mode collapse using second-order gradient information. To do so, we analyse the loss surface through its Hessian eigenvalues, and show that mode collapse is related to the convergence towards sharp minima. In particular, we observe how the eigenvalues of the G are directly correlated with the occurrence of mode collapse. Finally, motivated by these findings, we design a new optimization algorithm called nudged-Adam (NuGAN) that uses spectral information to overcome mode collapse, leading to empirically more stable convergence properties.
In the modern knowledge-based and digital economy, the value of knowledge is growing relative to other assets and new intellectual property is being created at an ever-increasing rate. Therefore, the ability to find non-trivial solutions, systematically generate new concepts, and create intellectual property rapidly become crucial to achieving competitive advantage and leveraging the intellectual potential of organizations.
With economic weight shifting toward net zero, now is the time for ECAs, Exim-Banks, and PRIs to lead. Despite previous success, aligning global economic governance to climate goals requires additional activities across export finance and investment insurance institutions. The new research project initiated by Oxford University, ClimateWorks Foundation, and Mission 2020 including other practitioners and academics from institutions such as Atradius DSB, Columbia University, EDC, FMO and Offenburg University focuses on reshaping future trade and investment governance in light of climate action. The idea of a ‘Berne Union Net Zero Club’ is an important item in a potential package of reforms. This can include realigning mandates and corporate strategies, principles of intervention, as well as ECA, Exim-Bank and PRI operating models in order to accelerate net zero transformation. Full transparency regarding Berne Union members’ activities would be an excellent starting point. We invite all interested parties in the sector to come together to chart our own path to net zero
Additive manufacturing (AM) and in particular the application of 3D multi material printing offers completely new production technologies thanks to the degree of freedom in design and the simultaneous processing of several materials in one component. Today's CAD systems for product development are volume-based and therefore cannot adequately implement the multi-material approach. Voxel-based CAD systems offer the advantage that a component can be divided into many voxels and different materials and functions can be assigned to these voxels. In this contribution two voxel-based CAD systems will be analyzed in order to simplify the AM on voxel level with different materials. Thus, a number of suitable criteria for evaluating voxel-based CAD systems are being developed and applied. The results of a technical-economic comparison show the differences between the voxel-based systems and disclose their disadvantages compared to conventional CAD systems. In order to overcome these disadvantages, a new method is therefore presented as an approach that enables the voxelization of a component in a simple way based on a conventional CAD model. The process chain of this new method is demonstrated using a typical component from product design. The results of this implementation of the new method are illustrated and analyzed.
Multiple Object Tracking (MOT) is a long-standing task in computer vision. Current approaches based on the tracking by detection paradigm either require some sort of domain knowledge or supervision to associate data correctly into tracks. In this work, we present an unsupervised multiple object tracking approach based on visual features and minimum cost lifted multicuts. Our method is based on straight-forward spatio-temporal cues that can be extracted from neighboring frames in an image sequences without superivison. Clustering based on these cues enables us to learn the required appearance invariances for the tracking task at hand and train an autoencoder to generate suitable latent representation. Thus, the resulting latent representations can serve as robust appearance cues for tracking even over large temporal distances where no reliable spatio-temporal features could be extracted. We show that, despite being trained without using the provided annotations, our model provides competitive results on the challenging MOT Benchmark for pedestrian tracking.
We introduce an open source python framework named PHS-Parallel Hyperparameter Search to enable hyperparameter optimization on numerous compute instances of any arbitrary python function. This is achieved with minimal modifications inside the target function. Possible applications appear in expensive to evaluate numerical computations which strongly depend on hyperparameters such as machine learning. Bayesian optimization is chosen as a sample efficient method to propose the next query set of parameters.
(1) Background: Little is known about the baroque composer Domenico Scarlatti (1685-1757), whose life was centred behind closed doors at the royal court in Spain. There are no reports about his illnesses. From his compositions, mainly for harpsichord, an outstanding virtuosity can be read. (2) Case Presentation: In this case report, the only known oil painting of Domenico Scarlatti is presented, on which he is about 50 years old. In it one recognizes conspicuous hands with hints of watch glass nails and drumstick fingers. (3) Discussion: Whether Scarlatti had chronic hypoxia of peripheral body regions as a sign of, e.g., bronchial cancer or a severe heart disease, is not known. (4) Conclusions: The above-mentioned signs recorded in the oil painting, even if they were not interpretable at that time, are clearly represented and recorded for us and are open to diagnostic discussion from today's point of view.
In the area of cloud computing, judging the fulfillment of service-level agreements on a technical level is gaining more and more importance. To support this we introduce privacy preserving set relations as inclusiveness and disjointness based ao Bloom filters. We propose to compose them in a slightly different way by applying a keyed hash function. Besides discussing the correctness of set relations, we analyze how this impacts the privacy of the sets content as well as providing privacy on the sets cardinality. Indeed, our solution proposes to bring another layer of privacy on the sizes. We are in particular interested how the overlapping bits of a Bloom filter impact the privacy level of our approach. We concretely apply our solution to a use case of cloud security audit on access control and present our results with real-world parameters.
Deep generative models have recently achieved impressive results for many real-world applications, successfully generating high-resolution and diverse samples from complex datasets. Due to this improvement, fake digital contents have proliferated growing concern and spreading distrust in image content, leading to an urgent need for automated ways to detect these AI-generated fake images.
Despite the fact that many face editing algorithms seem to produce realistic human faces, upon closer examination, they do exhibit artifacts in certain domains which are often hidden to the naked eye. In this work, we present a simple way to detect such fake face images - so-called DeepFakes. Our method is based on a classical frequency domain analysis followed by basic classifier. Compared to previous systems, which need to be fed with large amounts of labeled data, our approach showed very good results using only a few annotated training samples and even achieved good accuracies in fully unsupervised scenarios. For the evaluation on high resolution face images, we combined several public datasets of real and fake faces into a new benchmark: Faces-HQ. Given such high-resolution images, our approach reaches a perfect classification accuracy of 100% when it is trained on as little as 20 annotated samples. In a second experiment, in the evaluation of the medium-resolution images of the CelebA dataset, our method achieves 100% accuracy supervised and 96% in an unsupervised setting. Finally, evaluating a low-resolution video sequences of the FaceForensics++ dataset, our method achieves 91% accuracy detecting manipulated videos.
Recent studies have shown remarkable success in image-to-image translation for attribute transfer applications. However, most of existing approaches are based on deep learning and require an abundant amount of labeled data to produce good results, therefore limiting their applicability. In the same vein, recent advances in meta-learning have led to successful implementations with limited available data, allowing so-called few-shot learning.
In this paper, we address this limitation of supervised methods, by proposing a novel approach based on GANs. These are trained in a meta-training manner, which allows them to perform image-to-image translations using just a few labeled samples from a new target class. This work empirically demonstrates the potential of training a GAN for few shot image-to-image translation on hair color attribute synthesis tasks, opening the door to further research on generative transfer learning.
In this preliminary report, we present a simple but very effective technique to stabilize the training of CNN based GANs. Motivated by recently published methods using frequency decomposition of convolutions (e.g. Octave Convolutions), we propose a novel convolution scheme to stabilize the training and reduce the likelihood of a mode collapse. The basic idea of our approach is to split convolutional filters into additive high and low frequency parts, while shifting weight updates from low to high during the training. Intuitively, this method forces GANs to learn low frequency coarse image structures before descending into fine (high frequency) details. Our approach is orthogonal and complementary to existing stabilization methods and can simply plugged into any CNN based GAN architecture. First experiments on the CelebA dataset show the effectiveness of the proposed method.
Excellent organisations require targeted strategies to implement their vision and mission, deploying a stakeholder-focused approach. As part of evidence-based policy making, it is a common approach to measure government financing vehicles’ results. A state-of-the-art method in quantitative benchmarking to overcome the challenge of considering multiple inputs and outputs is Data Envelopment Analysis (DEA). Descriptive statistics and explorative-qualitative approaches are also applied in a modern ECA benchmarking model to substantiate DEA results and put them into perspective. This enabler-result model provides a holistic view and allows to identify top performing ECAs and Exim-Banks, providing the opportunity for inefficient institutions to learn from their most productive peers. This best practice approach for strategic benchmarking enables the senior management to develop and implement a cutting-edge strategy, and increase value for key stakeholders.
Micro-cracks give rise to non-analytic behavior of the stress-strain relation. For the case of a homogeneous spatial distribution of aligned flat micro-cracks, the influence of this property of the stress-strain relation on harmonic generation is analyzed for Rayleigh waves and for acoustic wedge waves with the help of a simple micromechanical model adopted from the literature. For the efficiencies of harmonic generation of these guided waves, explicit expressions are derived in terms of the corresponding linear wave fields. The initial growth rates of the second harmonic, i.e., the acoustic nonlinearity parameter, has been evaluated numerically for steel as matrix material. The growth rate of the second harmonic of Rayleigh waves has also been determined for microcrack distributions with random orientation, using a model expression for the strain energy in terms of strain invariants known in a geophysical context.
Our media-artistic performances and installations, INTERCORPOREAL SPLITS (2010–2013), BUZZ (2014–2015), W ASTELAND (2015–2016), as well as our new collaboration with Bruno Latour , DE\GLOBALIZE (2018–2020), are not just about polyphony. Here, however, we rediscover them under this heading, thus giving them a new twist, while mapping out issues, mechanisms and functional modes of the polyphonic.
Using patent information for identification of new product features with high market potential
(2014)
The communication technologies for automatic me-ter reading (smart metering) and for energy production and distribution networks (smart grid) have the potential to be one of the first really highly scaled machine-to-machine-(M2M)-applications. During the last years two very promising devel-opments around the wireless part of smart grid communication were initialized, which possibly have an impact on the markets far beyond Europe and far beyond energy automation. Besides the specifications of the Open Metering System (OMS) Group, the German Federal Office for Information Security (Bundesamt für Sicherheit in der Informationstechnik, BSI) has designed a protection profile (PP) and a technical directive (TR) for the communication unit of an intelligent measurement sys-tem (smart meter gateway), which were released in March 2013. This design uses state-of-the-art technologies and prescribes their implementation in real-life systems. At first sight the expenditures for the prescribed solutions seem to be significant. But in the long run, this path is inevitable and comes with strategic advantages.
Multi-agent systems are a subject of continuously increasing interest in applied technical sciences. Smart grids are one evolving field of application. Numerous smart grid projects with various interpretations of multi-agent systems as new control concept arose in the last decade. Although several theoretical definitions of the term ‘agent’ exist, there is a lack of practical understanding that might be improved by clearly distinguishing the agent technologies from other state-of-the-art control technologies. In this paper we clarify the differences between controllers, optimizers, learning systems, and agents. Further, we review most recent smart grid projects, and contrast their interpretations with our understanding of agents and multi-agent systems. We point out that multi-agent systems applied in the smart grid can add value when they are understood as fully distributed networks of control entities embedded in dynamic grid environments; able to operate in a cooperative manner and to automatically (re-)configure themselves.
The Advanced Innovation Design Approach is a holistic methodology for enhancing innovative and competitive capability of industrial companies. AIDA can be considered as an open mindset, an individually adaptable range of strongest innovation techniques such as comprehensive front-end innovation process, advanced innovation methods, best tools and methods of the TRIZ methodology, organizational measures for accelerating innovation, IT-solutions for Computer-Aided Innovation, and other innovation methods, elaborated in the recent decade in the industry and academia
The European TRIZ Association ETRIA acts as a connecting link between scientific institutions, universities and other educational organizations, industrial companies and individuals concerned with conceptual and practical questions relating to organization of innovation process, invention methods, and innovation knowledge. In the meantime, more than TFC 1000 papers or presentation of scientists, educators, and practitioners from all over the world are available at the official ETRIA website. Numerous research projects were supported or funded by the European Commission.
Risk aversion, financing and real servicThe Global CEO Survey was launched in 2015 by researchers from Offenburg University, the University of Westminster and the London School of Economics and Political Science (LSE) to better understand and discover what factors influence exporters’ demand for credit insurance. Although some scholars discussed aspects of corporate insurance demand with regard to exporters, there is limited research concerning the demand for export credit insurance associated with firm-specific factors. Only few empirical studies support existing theories on corporate insurance demand and export credits. This project investigates and fills the relevant gap of official export credit insurance demand.es
Electrolyte-Gated Field-Effect Transistors Based on Oxide Semiconductors: Fabrication and Modeling
(2017)
The aim of this data collection is to enforce evidence of SCS effectiveness in treating neuropathic chronic pain and the very low percentage of undesired side effects of complications reported in our case series suggests that all implants should be performed by similarly well-trained and experienced professionals.
The M-Bus protocol (EN13757) is in widespread use for metering applications within home area and neighborhood area networks, but lacks a strict specification. This may lead to incompatibilities in real-life installations and to problems in the deployment of new M-Bus networks. This paper presents the development of a novel testbed to emulate physical Metering Bus (M-Bus) networks with different topologies and to allow the flexible verification of real M-Bus devices in real-world scenarios. The testbed is designed to support device manufacturers and service technicians in test and analysis of their devices within a specific network before their installation. The testbed is fully programmable, allowing flexible changes of network topologies, cable lengths and types. Itis easy to use, as only the master and the slaves devices have to be physically connected. This allows to autonomously perform multiple tests, including automated regression tests. The testbed is available to other researchers and developers. We invite companies and research institutions to use this M-Bus testbed to increase the common knowledge and real-world experience.
A Survey of Channel Measurements and Models for Current and Future Railway Communication Systems
(2016)
Nowadays, it is assumed of many applications, companies and parts of the society to be always available online. However, according to [Times, Oct, 31 2011], 73% of the world population do not use the internet and thus aren't “online” at all. The most common reasons for not being “online” are expensive personal computer equipment and high costs for data connections, especially in developing countries that comprise most of the world’s population (e.g. parts of Africa, Asia, Central and South America). However it seems that these countries are leap-frogging the “PC and landline” age and moving directly to the “mobile” age. Decreasing prices for smart phones with internet connectivity and PC-like operating systems make it more affordable for these parts of the world population to join the “always-online” community. Storing learning content in a way accessible to everyone, including mobile and smart phones, seems therefore to be beneficial. This way, learning content can be accessed by personal computers as well as by mobile and smart phones and thus be accessible for a big range of devices and users. A new trend in the Internet technologies is to go to “the cloud”. This paper discusses the changes, challenges and risks of storing learning content in the “cloud”. The experiences were gathered during the evaluation of the necessary changes in order to make our solutions and systems “cloud-ready”.
The combination of fossil-derived fuels with ethanol and methanol has acquired relevance and attention in several countries in recent years. This trend is strongly affected by market prices, constant geopolitical events, new sustainability policies, new laws and regulations, etc. Besides bio-fuels these materials also include different additives as anti-shock agents and as octane enhancer. Some of the chemical compounds in these additives may have harmful properties for both environment and public health (besides the inherent properties, like volatility). We present detailed Raman spectral information from toluene (C7H8) and ethanol (C2H6O) contained in samples of ElO gasoline-ethanol blends. The spectral information has been extracted by using a robust, high resolution Fourier-Transform Raman spectrometer (FT-Raman) prototype. This spectral information has been also compared with Raman spectra from pure additives and with standard Raman lines in order to validate its accuracy in frequency. The spectral information is presented in the range of 0 cm-1 to 3500 cm-1 with a resolution of 1.66cm-1. This allows resolving tight adjacent Raman lines like the ones observed around 1003cm-1 and 1030cm-1 (characteristic lines of toluene). The Raman spectra obtained show a reduced frequency deviation when compared to standard Raman spectra from different calibration materials. The FT-Raman spectrometer prototype used for the analysis consist basically of a Michelson interferometer and a self-designed photon counter cooled down on a Peltier element arrangement. The light coupling is achieved with conventional62.5/125μm multi-mode fibers. This FT-Raman setup is able to extract high resolution and frequency precise Raman spectra from the additives in the fuels analyzed. The proposed prototype has no additional complex hardware components or costly software modules. The mechanical and thermal disturbances affecting the FT-Raman system are mathematically compensated by accurately extracting the optical path information of the Michelson interferometer. This is accomplished by generating an additional interference pattern with a λ = 632.8 nm Helium-Neon laser (HeNe laser). It enables the FT-Raman system to perform reliable and clean spectral measurements from the materials under observation.
Formal Description of Inductive Air Interfaces Using Thévenin's Theorem and Numerical Analysis
(2014)
With the development of new integrated circuits to interface radio frequency identification protocols, inductive air interfaces have become more and more important. Near field communication is not only able to communicate, but also possible to transfer power wirelessly and to build up passive devices for logistical and medical applications. In this way, the power management on the transponder becomes more and more relevant. A designer has to optimize power consumption as well as energy harvesting from the magnetic field. This paper discusses a model with simple equations to improve transponder antenna matching. Furthermore, a new numerical analysis technique is presented to calculate the coupling factors, inductions, and magnetic fields of multiantenna systems.
Hybrid SPECT/US
(2014)
A benchmark analysis of Long Range (LoRaTM) Communication at 2.45 Ghz for safety applications
(2014)
Creating growth through trade is an important part of the policy approach of many economies. For decades, many member countries of the Organisation for Economic Co-operation and Development (OECD) have cooperated in a fair competition for the benefit of their national exporters. The countries’ official export credit agencies (ECAs) have established and jointly improved rules and regulations for export credit and political risk insurance. However, new players such as China, Russia or other fast developing countries have now joined the list of top exporting nations. As these countries have established their own ECAs, there is a need to introduce rules and regulations on global standards for financial terms as well as truly international norms ensuring ‘ethical’ trading behaviour.
But how will government support for foreign trade look like in the future? Will global standards for export credit and political risk insurance become reality by 2020? And how will strict rules and regulations for officially supported export credits and FDI regarding ethics, human rights and the environment impact growth through trade in general, or exporters in particular? These are questions addressed by the thirty eight contributions to Global Policy’s third eBook entitled ‘The Future of Foreign Trade Support – Setting Global Standards for Export Credit and Political Risk Insurance’, guest edited by Andreas Klasen and Fiona Bannert.
All business is local
(2016)
Extended Performance Measurements of Scalable 6LoWPAN Networks in an Automated Physical Testbed
(2015)
IPv6 over Low power Wireless Personal Area Networks, also known as 6LoWPAN, is becoming more and more a de facto standard for such communications for the Internet of Things, be it in the field of home and building automation, of industrial and process automation, or of smart metering and environmental monitoring. For all of these applications, scalability is a major precondition, as the complexity of the networks continuously increase. To maintain this growing amount of connected nodes a various 6LoWPAN implementations are available. One of the mentioned was developed by the authors' team and was tested on an Automated Physical Testbed for Wireless Systems at the Laboratory Embedded Systems and Communication Electronics of Offenburg University of Applied Sciences, which allows the flexible setup and full control of arbitrary topologies. It also supports time-varying topologies and thus helps to measure performance of the RPL implementation. The results of the measurements prove an excellent stability and a very good short and long-term performance also under dynamic conditions. In all measurements, there is an advantage of minimum 10% with regard to the average times, like global repair time; but the advantage with reagr to average values can reach up to 30%. Moreover, it can be proven that the performance predictions from other papers are consistent with the executed real-life implementations.
The energy supply of Offenburg University of Applied Sciences (HS OG) was changed from separate generation to trigeneration in 2007/2008. Trigeneration was installed for supplying heat, cooling and electrical power at HS OG. In this paper, trigeneration process and its modes of operation along with the layout of the energy facility at HS OG were described. Special emphasis was given to the operation schemes and control strategies of the operation modes: winter mode, transition mode and summer mode. The components used in the energy facility were also outlined. Monitoring and data analysis of the energy system was carried out after the commissioning of trigeneration in the period from 2008 to 2011. Thus, valuable performance data was obtained.
Several cloud schedulers have been proposed in the literature with different optimization goals such as reducing power consumption, reducing the overall operational costs or decreasing response times. A less common goal is to enhance the system security by applying specific scheduling decisions. The security risk of covert channels is known for quite some time, but is now back in the focus of research because of the multitenant nature of cloud computing and the co-residency of several per-tenant virtual machines on the same physical machine. Especially several cache covert channels have been identified that aim to bypass a cloud infrastructure's sandboxing mechanism. For instance, cache covert channels like the one proposed by Xu et. al. use the idealistic scenario with two alternately running colluding processes in different VMs accessing the cache to transfer bits by measuring cache access time. Therefore, in this paper we present a cascaded cloud scheduler coined C 3 -Sched aiming at mitigating the threat of a leakage of customers data via cache covert channels by preventing processes to access cache lines alternately. At the same time we aim at maintaining the cloud performance and minimizing the global scheduling overhead.
Not only is the number of new devices constantly increasing, but so is their application complexity and power. Most of their applications are in optics, photonics, acoustic and mobile devices. Working speed and functionality is achieved in most of media devices by strategic use of digital signal processors and microcontrollers of the new generation. Considering all these premises of media development dynamics, the authors present how to integrate microcontrollers and digital signal processors in the curricula of media technology lectures by using adequate content. This also includes interdisciplinary content that consists of using the acquired knowledge in media software. These entries offer a deeper understanding of photonics, acoustics and media engineering.
The design of control systems in large-scale CPV power plants will be more challenging in the future. Reasons are the increasing size of power plants, the requirements of grid operators, new functions, and new technological trends in industrial automation or communication technology. Concepts and products from fixed-mounted PV can only partly be adopted since control systems for sun-tracking installations are considerable more complex due to the higher quantity of controllable entities. The objective of this paper is to deliver design considerations for next generation control systems. Therefore, the work identifies new applications of future control systems categorized into operation, monitoring and maintenance domains. The key-requirements of the technical system and the application layer are identified. In the resulting section, new strategies such as a more decentralized architecture are proposed and design criteria are derived. The contribution of this paper should allow manufacturers and research institutes to consider the design criteria in current development and to place further research on new functions and control strategies precisely.
Diode-array planar chromatography is a versatile tool for identification of pharmaceutical substances In this paper thirty-three compounds with benzodiazepine properties were investigated and the separating conditions for silica gel HPTLC plates and three mobile phases were optimized. Diode-array HPTLC makes it possible to identify all the compounds with high certainty down to a level of 20 ng. An algorithm for spectral recognition which is combined with R F values from the three separation steps into one fit factor is presented. This set of data is unique for each of the compounds investigated and enables unequivocal identification. The method is rapid, inexpensive, and sensitive down to a level of 20 ng mL −1.
Geothermal Energy in Germany
(2009)
This paper focuses on the effects of differential mode delay (DMD) on the bandwidth of multimode optical fibres. First an analytical solution for the computation of the differential mode time delay is presented. The electrical field of each mode is calculated by the numerical solution of the Helmholtz equation. Based on this solution the modal power distribution as well as the fibre's impulse response under different launching conditions can be obtained.
Next, the refractive-index profile of two fibres is modelled on the basis of DMD measurements. It is shown that these measurements provide enough information to predict the fibre's propagation characteristics under different launch conditions (excitation conditions).
An interlaboratory comparison was carried out to evaluate the effectiveness of a method based on HPTLC in which reagent-free derivatization is followed by UV/fluorescence detection. The method was tested for the determination of sucralose (C12H19C13O8; (2R,3R,4R,5S,6R)-2-[(2R,3S,4S,5S)-2,5-bis(chloromethyl)-3,4-dihydroxyoxolan-2-yl]oxy-5-chloro-6-hydroxymethyl)oxane-3, 4-diol; CAS Registry No. 56038-13-2) in carbonated and still beverages at the proposed European regulatory limits. For still beverages, a portion of the sample was diluted with methanol-water. For carbonated beverages, a portion of the sample was degassed in an ultrasonic bath before dilution. Turbid beverages were filtered after dilution through an HPLC syringe filter. The separation of sucralose was performed by direct application on amino-bonded (NH2) silica gel HPTLC plates (no cleanup needed) with the mobile phase acetonitrile-water. Sucralose was determined after reagent-free derivatization at 190 degrees C; it was quantified by measurements of both UV absorption and fluorescence. The samples, both spiked and containing sucralose, were sent to 14 laboratories in five different countries. Test portions of a sample found to contain no sucralose were spiked at levels of 30.5, 100.7, and 299 mg/L. Recoveries ranged from 104.3 to 124.6% and averaged 112% for determination by UV detection; recoveries ranged from 98.4 to 101.3% and averaged 99.9% for determination by fluorescence detection. On the basis of the results for spiked samples (blind duplicates at three levels), as well as sucralose-containing samples (blind duplicates at three levels and one split level), the values for the RSDr ranged from 10.3 to 31.4% for determinations by UV detection and from 8.9 to 15.9% for determinations by fluorescence detection. The values for the RSDR values ranged from 13.5 to 31.4% for determinations by UV detection and from 8.9 to 20.7% for determinations by fluorescence detection.