• search hit 1 of 2
Back to Result List

Synthesis, Crystal Structure and Catalytic Behavior of Homo- and Heteronuclear Coordination Polymers [M(tdc)(bpy)] (M2+ = Fe2+, Co2+, Zn2+, Cd2+; tdc2– = 2,5-thiophenedicarboxylate)

  • A series of isostructural 3D coordination polymers (3)∞[M(tdc)(bpy)] (M(2+) = Zn(2+), Cd(2+), Co(2+), Fe(2+); tdc(2-) = 2,5-thiophenedicarboxylate; bpy = 4,4'-bipyridine) was synthesized and characterized by X-ray diffraction, thermal analysis, and gas adsorption measurements. The materials show high thermal stability up to approximately 400 °C and a solvent induced phase transition. SingleA series of isostructural 3D coordination polymers (3)∞[M(tdc)(bpy)] (M(2+) = Zn(2+), Cd(2+), Co(2+), Fe(2+); tdc(2-) = 2,5-thiophenedicarboxylate; bpy = 4,4'-bipyridine) was synthesized and characterized by X-ray diffraction, thermal analysis, and gas adsorption measurements. The materials show high thermal stability up to approximately 400 °C and a solvent induced phase transition. Single crystal X-ray structure determination was successfully performed for all compounds after the phase transition. In the zinc-based coordination polymer, various amounts of a second type of metal ions such as Co(2+) or Fe(2+) could be incorporated. Furthermore, the catalytic behavior of the homo- and heteronuclear 3D coordination polymers in an oxidation model reaction was investigated.show moreshow less

Export metadata

Additional Services

Share in Twitter Search Google Scholar
Metadaten
Author:Florian Kettner, Christian Worch, Jens MöllmerGND, Roger Gläser, Reiner StaudtGND, Harald Krautscheid
Creating Corporation:American Chemical Society
Year of Publication:2013
Language:English
GND Keyword:Katalyse; Kristallstruktur; Polymere; Synthese
Parent Title (English):Inorganic Chemistry
Volume:52
Issue:15
ISSN:0020-1669
First Page:8738
Last Page:8742
Document Type:Article (reviewed)
Institutes:Hochschule Offenburg / Bibliografie
Acces Right:Frei zugänglich
Release Date:2018/04/18
Licence (German):License LogoEs gilt das UrhG
DOI:https://doi.org/10.1021/ic400857s
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=23865443